You can purchase a private SSL from the
SSL
Certificate page. This certificate could be easily
enabled via the SSL support for Magento through the Admin
area -> System -> Configuration -> Web. There you can
define the insecure (non-SSL) and secure (SSL) URLs:

Bear in mind, that the SSL connection over HTTPS is
slower than the HTTP, thus the secured connection should be
applied only to the pages that contain and transfer
sensitive information.